|Title||구두발표 : 구두발표(OA) - 농업환경 및 토양,수질 분야 ; OA-03 : 사양토에서 왕겨 바이오차 시용에 따른 암모늄태 질소(NH4-N) 흡착특성 및 반응속도 [Adsorption Characteristics and Kinetic Models of Ammonium Nitrogen using Biochar from Rice hull in Sandy loam]|
|Publication Type||Journal Article|
|Year of Publication||2015|
|Authors||Choi, Yong Su, Kim Sung Chul, and Shin JoungDu|
|Journal||한국환경농학회 학술발표논문집 (Korea Environmental Agriculture Conference)|
Objective of this study was to investigate adsorption characteristic and kinetic model of NH4-N to biochar produced from rice hull in respective to mitigation of greenhouse gases. NH4-N concentration was analyzed by UV spectrophotometer. For the experiment, the soil texture used in this study was sandy loam, and application rate of chemical fertilizer and pig compost were 420-200-370 kg ha-1 (N-P-K) and 5,500 kg ha-1 as recommended amount after soil test for corn cultivation. Biochar treatments were 0.2-5% to soil weigh. Its adsorption characteristic was investigated with application of Langmuir isotherm, and pseudo-first order kinetic model and pseudo-second order kinetic model were used as kinetic models. Adsorption amount and removal rates of NH4-N were 39.3 mg g-1 and 28.0% in 0.2% biochar treatment, respectively. The sorption of NH4-N to biochar was fitted well by Langmuir model because it was observed that dimensionless constant (RL) was 0.48. The maximum adsorption amount (qm) and binding strength constant (b) were calculated as 4.1 mg g-1 and 0.01 L mg-1 in Langmuir isotherm, respectively. The pseudo-second order kinetic models was more appropriate than pseudo-first order kinetic model for high correlation coefficient (r2) of pseudo-second order kinetic model. Therefor, biochar produced from rice hull could reduce N2O by adsorbing NH4-N to biochar cooperated in sandy loam.